High-Quality Calcium Carbide for Efficient Desulfurization in Steelmaking: Key Benefits and Application Insights

Longwei Chemical
2026-01-31
Special report
This专题报道 explores the critical role of high-purity calcium carbide (CaC₂) in efficient desulfurization within the steel industry. It explains the chemical reaction mechanisms, highlights its stability at high temperatures, and examines key operational factors such as temperature, particle size, and addition timing. Supported by real-world case studies from Xinjiang steel plants and data-driven process optimization strategies, this article provides actionable insights for improving sulfur removal efficiency while reducing costs. Practical troubleshooting guides and visual aids enhance technical clarity for metallurgical engineers and plant operators. The content aligns with current industry research trends to ensure relevance and practical value.

High-Quality Calcium Carbide for Efficient Desulfurization in Steelmaking

In the global steel industry, achieving consistent quality and cost efficiency remains a top priority. One often overlooked yet powerful solution is high-purity calcium carbide (CaC₂), which has proven to be an effective desulfurizing agent in both converter and iron pretreatment processes.

How Calcium Carbide Works: The Science Behind the Process

When introduced into molten iron or steel at temperatures above 1,500°C, calcium carbide undergoes a key chemical reaction:

CaC₂ + [O] → CaO + 2[C] → CaS + CO↑

This process effectively removes sulfur from molten metal by forming calcium sulfide (CaS), which floats to the slag layer. According to data from Xinjiang-based steel mills, using premium-grade calcium carbide (≥85% purity) can reduce sulfur content from 0.04% to under 0.015%, improving product quality while reducing reagent consumption by up to 12% compared to traditional methods.

Key Factors That Influence Performance

Successful desulfurization depends on three main variables:

  • Temperature: Optimal range is 1,500–1,650°C — below this, reaction kinetics slow down significantly.
  • Particle Size: Ideal grain size: 5–15 mm. Smaller particles increase surface area but may cause premature oxidation.
  • Addition Timing: For iron pretreatment, adding after tapping ensures better mixing and minimizes loss due to splashing.

Case studies from two major plants in Xinjiang show that adjusting these parameters based on real-time temperature monitoring led to a 20% reduction in operational inconsistencies over six months.

Common Challenges & Practical Solutions

Operators often face issues like uneven desulfurization or excessive slag formation. Based on field reports:

Issue Likely Cause Recommended Fix
Incomplete desulfurization Low temperature (<1,450°C) Preheat ladle to 1,550°C before addition
Excessive slag volume Too fine particle size (<5mm) Use controlled crushing to maintain 8–12mm range

These troubleshooting tips are backed by over 30 technical visits across Asia-Pacific steel facilities and have been validated through lab-scale simulations and industrial trials.

Ready to Improve Your Steel’s Sulfur Control?

We offer certified high-purity calcium carbide tailored for your specific process conditions — with technical support, batch consistency, and delivery reliability you can count on.

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